So this wallpaper was made for two people:
Ashe: As per request/suggestion.
Liz/Eyrx: As a birthday present. :'DD

So basically, I actually vectored the image myself. I know, I'm amazed too. My very first vector! (Of this scan) Took me two full days, and over 150 layers (and that's only because I clumped a lot of stuff onto a single layer whenever I could), but I finally finished it this afternoon. It was actually a lot of fun to do. Tedious, but still fun. :3 I loved how accomplished I felt the second I finished it. *-*
So after vectoring, I made a sky, found a mountain stock from DeviantArt and added some effects, filters and textures and got it to where it is now.
I know nearly nothing in the wallpaper is perfect, but I'm proud of the outcome. =)

Crits + Comms =

EDIT-
I vectored in his eyebrows. XD OOPS.
Thanks xanime4lifex for the heads up.